Robert Mathers

Photo of Robert Mathers
Professor, Science
Office Phone
Office Location
Engineering, 122B
0002 ADMINISTRATION BLDG
NEW KENSINGTON, PA 15068
Research Interests

polymer chemistry, catalysis, renewable resources, green chemistry, sustainable materials

Publications

Combinatorial Biomaterials Discovery Strategy to Identify New Macromolecular Cryoprotectants, ACS MACRO LETTERS - 2020
Collaborators: Christopher Stubbs, Author; Kathryn Murray, Author; Toni Ishibe, Author; Matthew Gibson, Author

Ranking environmental degradation trends of plastic marine debris based on physical properties and molecular structure, NATURE COMMUNICATIONS - 2020
Collaborators: Kyungjun Min, Author; Joseph Cuiffi, Author

Synthesis and Characterization of a Leucine-Based Block Co-Polypeptide: The Effect of the Leucine Zipper on Self-Assembly, BIOMACROMOLECULES - 2020
Collaborators: Brooke Barnes, Author; Taylor Jenkins, Author; Lauren Stein, Author; Masita Wicaksana, Author; Melissa Pasquinelli, Author; Daniel Savin, Author

Toward Next-Generation Biohybrid Catalyst Design: Influence of Degree of Polymerization on Enzyme Activity, BIOCONJUGATE CHEMISTRY - 2020
Collaborators: Marina Kovaliov, Author; Thaiesha Wright, Author; Boyle Cheng, Author; Xiangyu Zhang, Author; Dong Meng, Author; Katarzyna Szczesniak, Author; Jacek Jenczyk, Author; Stefan Jurga, Author; Devora Cohen-Karni, Author; Richard Page, Author; Dominik Konkolewicz, Author; Saadyah Averick, Author

Dyeing to Degrade: A Bioplastics Experiment for College and High School Classrooms, Journal of Chemical Education - 2019
Collaborators: Cassandra Knutson, Author; Abby Hilker, Author; Zachary Tolstyka, Author; Constance Anderson, Author; Perry Wilbon, Author; Michael Wentzel, Author; Angela Perkins, Author; Jane Wissinger, Author

Predicting Monomers for Use in Aqueous Ring-Opening Metathesis Polymerization-Induced Self-Assembly, ACS MACRO LETTERS - 2019
Collaborators: Spyridon Varlas, Author; Jeffrey Foster, Author; Lucy Arkinstall, Author; Joseph Jones, Author; Robert Keogh, Author; Rachel O'Reilly, Author

SuFEx-based strategies for the preparation of functional particles and cation exchange resins, CHEMICAL COMMUNICATIONS - 2019
Collaborators: Andrew Kassick, Author; Li Chen, Author; Marina Kovaliov, Author; Jason Locklin, Author; Saadyah Averick, Author

Uniform Biodegradable Fiber-Like Micelles and Block Comicelles via "Living" Crystallization-Driven Self-Assembly of Poly(-lactide) Block Copolymers: The Importance of Reducing Unimer Self-Nucleation via Hydrogen Bond Disruption, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - 2019
Collaborators: Yunxiang He, Author; Jean-Charles Eloi, Author; Robert Harniman, Author; Robert Richardson, Author; George Whittell, Author; Andrew Dove, Author; Rachel O'Reilly, Author; Ian Manners, Author

Quantitative Measurements of Polymer Hydrophobicity Based on Functional Group Identity and Oligomer Length, MACROMOLECULES - 2018
Collaborators: Nayanthara Dharmaratne, Author; Array Jouaneh, Terra Marie M., Author; Matthew Kiesewetter, Author

Predicting Monomers for Use in Polymerization-Induced Self-Assembly., Angewandte Chemie (International ed. in English) - November 26, 2018
Collaborators: J Foster, Author; S Varlas, Author; B Couturaud, Author; J Jones, Author; R Keogh, Author; R O'Reilly, Author

Overview of ring opening metathesis polymerizations (ROMP) and acyclic diene metathesis (ADMET) polymerizations with selected ruthenium and molybdenum complexes - May, 2018

1D vs. 2D shape selectivity in the crystallization-driven self-assembly of polylactide block copolymers - 2017
Collaborators: Maria Inam, Co-Author; Graeme Cambridge, Co-Author; Anais Pitto-Barry, Co-Author; Zachary Laker, Co-Author; Neil Wilson, Co-Author; Andrew Dove, Primary Author; Rachel O'Reilly, Primary Author

Functionalization of polyesters with multiple B vitamins - June 16, 2017
Collaborators: Andrew Soxman, Student Author; Jenna DeLuca, Student Author; Kylie Kinlough, Student Author; David Iwig, Co-Author

Unusual physical behaviour and polymorphic phase transitions in crystalline bicyclic anhydrides, Cryst. Eng. Comm. - 2017
Collaborators: Sebastian Jezowski, Primary Author; Stephen Monaco; Hemant Yennawar, Co-Author; Nichole Wonderling, Co-Author; Bohdan Schatschneider, Author

Zinc versus Magnesium: Orthogonal Catalyst Reactivity in Selective Polymerizations of Epoxides, Bio-derived Anhydrides and Carbon Dioxide, Chemistry – A European Journal - 2017
Collaborators: Prabhjot Saini, Co-Author; Giulia Fiorani, Co-Author; Charlotte Williams, Primary Author

Synthetic Design of Polyester Electrolytes Guided by Hydrophobicity Calculations, Macromolecules - 2016
Collaborators: Erol Yildirim, Author; Deivasagayam Dakshinamoorthy, Author; Matthew Peretic, Author; Melissa Pasquinelli, Author

Post Polymer Modification of Polyethylenimine with Citrate Esters: Selectivity and Hydrophobicity, RSC Advances - May, 2016
Collaborator: Justine Waggel, Student Author

Azeotropic Preparation of a C-Phenyl N-Aryl Imine: An Organic Chemistry Laboratory Experiment, Journal of Chemical Education
Collaborators: Lee Silverberg; John Tierney

Systematic Insights from Medicinal Chemistry to Discern the Nature of Polymer Hydrophobicity , Macromolecules
Collaborators: Andrew Magenau, Secondary Author; Jeffrey Richards, Student Author; Mellisa Pasquinelli, Secondary Author; Daniel Savin, Secondary Author

Moving Towards Greener Cationic Polymerizations - July, 2015
Collaborators: Stewart Lewis, Co-Author; D. Dakshinamoorthy, Co-Author

Exploration of the transition temperatures and crystal structure of highly crystalline poly(1,3-cyclohexadiene): An experimental and computational investigation, Polymer - October 2, 2014
Collaborators: Bohdan Schatschneider, Primary Author; Richard Gee; Nichole Wonderling

Diglycerol-based polyesters: melt polymerization with hydrophobic anhydrides., ChemSusChem - September 30, 2014
Collaborators: D Dakshinamoorthy, Author; A Weinstock, Author; K Damodaran, Author; D Iwig, Author

A biodegradable thermoset polymer made by esterification of citric acid and glycerol, Journal of Biomedical Materials Research Part A - May, 2014
Collaborators: Jeffrey Halpern, Author; Richard Urbanski, Author; Allison Weinstock, Author; David Iwig, Author; Horst von Recum, Author

Bulk and Solution Polymerization of Isobutene Using Tris(pentafluorophenyl)gallium and Tris(pentafluorophenyl)aluminum, Industrial & Engineering Chemistry Research - January 28, 2014
Collaborators: Nathan Hand, Student Author; Krishnan Damodaran, Author; Stewart Lewis, Primary Author

Crystallization of Poly(vinylidene fluoride) in Blends with Poly(methyl methacrylate-co-methacrylic acid) Copolymers, Macromolecular Chemistry and Physics - January, 2014
Collaborators: Forrest Landis, Primary Author; Stephen March, Author; D Dakshinamoorthy, Secondary Author

Towards sustainable polymer chemistry with homogeneous metal-based catalysts, Green Chem. - January, 2014
Collaborators: Kristin Schroder, Secondary Author; Krzysztof Matyjaszewski, Secondary Author; Kevin Noonan, Primary Author

Streamlining the conversion of biomass to polyesters: bicyclic monomers with continuous flow, Green Chem. - January, 2014
Collaborators: Deivasagayam Dakshinamoorthy, Secondary Author; Stewart Lewis, Secondary Author; Michael Cavazza, Secondary Author; Aaron Hoover, Secondary Author; David Iwig, Secondary Author; Krishnan Damodaran, Secondary Author

Overview of Controlled/Living Polymerization of Vinyl Monomers - January, 2014
Collaborators: Andrew Magneau, Secondary Author; Kristin Schröder, Secondary Author; Krzysztof Matyjaszewski, Secondary Author

Greener, cleaner preparation of high molecular weight polyisobutene, J. Green Materials - October, 2013
Collaborators: Liu Qian, Student Author; Krishnan Damodaran, Secondary Author; Bhaskar Godugu, Secondary Author; Stewart Lewis, Primary Author

NMR spectroscopic and computational investigations of RuHCl(CO)(PPh3)(3)catalyzed isomerization of 1,4-cyclohexadiene, Journal of Organometallic Chemistry - October, 2013
Collaborators: James Mao, Author; Krishnan Damodaran, Author

Lactide Cyclopolymerization Kinetics, X-ray Structure, and SolutionDynamics of (Bu-t-SalAmEE)Al and a Cautionary Tale Of Polymetalate Formation, Macromolecules - May, 2013
Collaborators: Solomon Reisberg, Author; Harry Hurley, Author; Joseph Tanski, Author; Array Getzler, Yutan D. Y. L., Author

Lactide cyclopolymerization by an alumitrane-inspired catalyst, Macromolecules - 2012
Collaborators: J Weil, Co-Author; Y Getzler, Co-Author

Substituted Tris(2-pyridylmethyl)amine Ligands for Highly Active ATRP Catalysts, ACS Macro Letters - July 30, 2012
Collaborators: K Schroeder, Co-Author; J Buback, Co-Author; D Konkolewicz, Co-Author; A Magneau, Co-Author; K Matyjaszewski, Co-Author

Aqueous cationic olefin polymerization using tris(pentafluorophenyl)gallium and aluminum, J. Polym. Sci., Part A: Polym. Chem. - April 1, 2012
Collaborator: S Lewis, Co-Author

Critical evaluation of microwave effect on radical (co)polymerizations, Macromolecular Rapid Communications - January 16, 2012
Collaborators: Y Kwak, Co-Author; K Matyjaszewski, Co-Author

How Well Can Renewable Resources Mimic Commodity Monomers and Polymers?, Journal of Polymer Science, Part A: Polymer Chemistry - January 1, 2012

2011
Collaborator: Michael Meier, Co-Editor

Advances in Acid Mediated Polymerizations - 2011
Collaborator: Stewart Lewis, Co-Author

Synthesis of renewable 1,3-cyclohexadiene using metathesis, isomerization, and cascade reactions with late-metal catalyst, Macromolecular Rapid Communications - June 3, 2011
Collaborators: Michael Shreve, Author; Etan Meyler, Author

Controlling Cross-Linking with renewable monoterpenes, Journal Polymer Science, Part A: Polymer Chemistry - June 20, 2011
Collaborators: Justin Delancey, Student Author; Matthew Cavazza, Student Author; Matthew Rendos, Student Author; Cory Ulisse, Student Author; Susan Palumbo, Student Author

Monoterpenes as polymerization solvents and monomers in polymer chemistry, Green Polymerization Methods: Catalysis, Renewable Resources, and Waste Reduction - April, 2011
Collaborator: Stewart Lewis, Co-Author

Handbook of Transition Metal Polymerization Catalysts - 2010
Collaborator: Ray Hoff, Co-Editor

Ring opening metathesis polymerizations (ROMP) and acyclic diene metathesis (ADMET) polymerizations with homogeneous ruthenium and molybdenum catalysts and initiators, Handbook of Transition Metal Polymerization Catalysts - 2010

Functional Hyperbranched Polymers using Ring Opening Metathesis Polymerization of Dicyclopentadiene with Monoterpenes, Macromolecules - February 10, 2009
Collaborators: Krishnan Damodaran, Secondary Author; M Rendo, Student Author; M Lavrich, Student Author

Ab initio analysis of the local coordination environment of oligomers derived from polymerizing 5-Norbornene-2-carboxylic acid, Journal of Molecular Structure: THEOCHEM - September, 2008
Collaborators: Krishnan Damodaran, Co-Author; N Dhumal, Co-Author

Solvent-free green polymerization method for polyesters using hydrocarboxylation reactions, Polymer Preprints (American Chemical Society, Division of Polymer Chemistry - August, 2008
Collaborators: Douglas Kushner; Valerie Schram

A general polymerization method using hydroalkoxylation and hydrocarboxylation reactions catalyzed by triflic acid, Macromolecules - January, 2008
Collaborators: C LeBlond, Secondary Author; Krishnan Damodaran, Secondary Author; D Kushner, Student Author; V Schram, Student Author

Renewable chain transfer agents for metallocene polymerizations: The effects of chiral monoterpenes on the polyolefin molecular weight and isotacticity, Journal of Polymer Science: Part A: Polymer Chemistry - 2007
Collaborator: Krishnan Damodaran

Ring open metathesis polymerizations in d-limonene: a renewable polymerization solvent and chain transfer agent for the synthesis of alkene macromonomers, Macromolecules - December, 2006
Collaborators: K McMahon; K Damodaran; C Retarides; D Kelley

Optically Transparent and High Molecular Weight Polyolefin Block Copolymers toward Self-Assembled Photonic Band Gap Materials, Macromolecules - February, 2006
Collaborators: J Yoon; G Coates; E Thomas

Influence of syndiotactic propylene units on the rheological parameters of poly(ethylene-propylene) copolymers, Macromolecules - October, 2005
Collaborators: L Fetters; J Lee; P Hustad; G Coates; L Archer; S Rucker; D Lohse

Structure and physical properties of syndiotactic polypropylene from living polymerization with Bis(phenoxyimine)-based Titanium catalysts, Macromolecules - November, 2004
Collaborators: C De Rosa; T Circelli; F Auriemma; G Coates

A SANS Study of the Self-Assembly in Solution of Syndiotactic Polypropylene Homopolymers, Syndiotactic Polypropylene-block-poly(ethylene-co-propylene) Diblock Copolymers, and an Alternating Atactic−Isotactic Multisegment Polypropylene, Macromolecules - September, 2004
Collaborators: A Radulescu; G Coates; D Richter; L Fetters

Fabrication of blended polyphenylenevinylene nanowires by scanned electrospinning, Journal of Photopolymerizations, Science and Technology - September, 2004
Collaborators: J Kameoka, Co-Author; R Ilic, Co-Author; D Czaplewski, Co-Author; G Coates, Co-Author; H Craighead, Co-Author

An efficient cross-metathesis functionalization of polyolefins, Chemical Communications - February, 2004
Collaborator: G Coates

Education

Ph D, Polymer Science, The University of Akron

BS, Chemistry, North Carolina State University